No hum, no ground loops and I am biamping.
Ground loops do not always show up as hum with volume turned way up with no music playing (of course really bad ground loops do). The insidious kind is when a power supply leakage affects ground on a device which adds modulated noise on your cabling as a function of power demands. The way to reduce this is to go balanced (so that the ground loop is induced equally in both positive and negative signals). You really can't detect this kind of insidious effect other than to observe the improved clarity of going to a properly balanced setup where grounds from different components are much less likely to get to your signal. The effect can of course be small when comparing good equipment that is well matched... nevertheless, several DB in better noise floor can usually be expected with XLR.