If I were you I would try first to integrate your Diablo with your current sub before taking a final decision. Read this post for more info about sub integration:
SubWoofer Help ASAP...
If however, the upgrade bug has bitten you already, then I would proceed with caution. Please do not take this the wrong way, but for somebody into hi-end audio who's father is a sound engineer your knowledge is surprisingly limited. I will try to clarify my statement as it is not intended to be arrogant.
Firstly, there are three main advantages of sub-monitors combos over large speakers: 1) the ability to place the sub in the place that will give you the best bass response, and 2) isolate the monitors from the strong vibrations generated by the subwoofer, and 3) the ability to place the monitor in the room in the position that will yield the most natural midrange and the best stereo image. Placing the Diablos on top of the subwoofers will negate the first two advantages.
Secondly, unless your speakers are symmetrically placed with respects to all room boundaries (often not even then) the response of the two speakers will never be the same. The larger the speaker the more it will interact with the room. Now, because of this, and also because you mention that the position of the speakers and listening chair are basically fixed, it is more likely that a sub monitor combo will work better than large speakers. However, since every room is different one can never be sure of this. (The Scalas have the bass adjustment knobs so they are more flexible than "normal" speakers.)
My advise will be to try to convince the dealer to bring the Scalas to you home. Make a deal with him, e.g. if you do not keep the Scalas you will pay him by the hour. Also, I would not trade in the Diablo but try to sell them myself (but this depends on where you are located). The Diablo are rather rare on the 2nd hand market so chances are you will get a better price for them than your dealer will offer you.
Finally, I want to make a comment about (2nd hand) Focal Scala speakers. For whatever reason I have seen quite a few Scala on the 2nd hand market (here in Europe they go as low as 12k euros). I've even started a thread about this here on audiogon but did not find out much why this is the case. Probably just a coincidence...
Good luck and keep us posted.
Paul