Leave tube gear on 24/7 if you have a large bank account and little worry about the cost of re-tubing with the good stuff. Otherwise, turn it off. After an hour of warm up, I doubt in a blind test you'd be able to tell the difference from a unit left on 24/7.
If you have solid state gear, then it likely sounds best if left on 24/7, but the "green" question comes into play. How much natural resources are are you comfortable wasting during the many hours you're not listening?
It's a personal decision.
Lots of folks driving Hummers. Lots of folks driving Prius.