Shadorne - wires are diodes. some impurities in the wire might create semiconductor junctions. As an example - copper oxide (wire in never 100% oxygen free) behaves like semiconductor. It was used to make rectifiers. Quote from Wikipedia below:
"Copper(I) oxide was the first substance known to behave as a semiconductor. Rectifier diodes based on this material were used industrially as early as 1924, long before silicon became the standard."
What happens inside of the wire is complicated. Electrons are not moving very fast (about 1/2" per second) and with AC signal they will never leave the cable. I would not polarize my cable with DC and loose my expensive electrons I paid for (ha ha).
"Copper(I) oxide was the first substance known to behave as a semiconductor. Rectifier diodes based on this material were used industrially as early as 1924, long before silicon became the standard."
What happens inside of the wire is complicated. Electrons are not moving very fast (about 1/2" per second) and with AC signal they will never leave the cable. I would not polarize my cable with DC and loose my expensive electrons I paid for (ha ha).

