Hi kijanki,
I am only speaking from personal experience and the way my feeble brain see's it. I've been around a whole bunch of Amps being built and modified in my time and have developed my perceptions.
When caps are charged and the electrolyte is active within them it somewhat pressurizes the inside of the cap. This pressure helps maintain the seal along with the electrolyte keeping the seal from drying out.
The problem comes when a cap is powered down and seals weaken.... I have seen caps leak.. or even explode when suddenly powered up. It is for this reason that on very old gear that hasn't been run that we always have brought their voltage up slowly on a variac to reform the caps and to protect the amp. It has been a problem is a few brands.... I believe that Mark Levinson had this problem at one time.
Again, this is simply my feeble perception... I'm a speaker guy.