I would question whether better sound after 25 hours is directly related to the tubes, or whether it is related to all the electronics warming up, and capacitors fully charging, etc. Of course, if all the gear is left on 24/7, then perhaps the 25 hours on the tubes is the cause.
No, I do not leave my tube gear on 24/7. 25 cumulative hours. I turn on my system and let it warm up for about 30 minutes with a source playing then I sat down for listening. Grant are you telling us that a New NOS tube sounds the same to you after a couple of hours burn-in than when you have accumulated , say 15 or 20 hours on it? I don't think so....